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9.1 FERMI'S GOLDEN RULE If a charge carrier, i.e. an electron or a hole, is moving within the body of a perfect crystal lattice which is free from all defects and with all atoms stationary, then it will continue in that state ad infinitum. Of course, such a situation is never reached, which implies that the charge carrier will change its state a process which is known as scattering. Quantum mechanical scattering is usually summarized in terms of Fermi's Golden Rule [174] which states the following: if an electron (or hole) in a state |i) of energy E\ experiences a time-dependent perturbation H which could scatter (transfer) it into any one of the final states |f) of energy Ef, then the lifetime of the carrier in state |i) is given by:

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Some terminology has been made obsolete by QuickBooks. The ledger is used in traditional accounting systems, but it does not have a lot of relevance to the QuickBooks system. You won t nd this term in its Glossary or Help Index, but it is a commonly used term, so it bears a mention and an explanation of its absence. A ledger was used to summarize the transactions recorded in a journal and to update the balance in each individual account affected by the transactions for a period of time, for example, weekly or monthly. Because QuickBooks instantly updates each affected account balance at the time that a transaction is entered, no ledger is necessary.

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9.2 PHONONS The massive atoms that constitute semiconductor crystals are all connected together by chemical bonds which are nominally covalent, although in compounds can have a degree of ionicity. These atoms are always in a state of continual motion, which because of the definite crystal lattice structure, is vibrational around an equilibrium position. The atoms vibrate even at the hypothetical zero of absolute temperature the so-called zero point energy (see Section 3.5). In some ways, the vibrations of these interconnected quantum particles (atoms) resembles a classical (macroscopic) system of a series of masses connected by springs. There are basically four different modes of vibration, as illustrated in Figs 9.1 and 9.2, each one of which is referred to as a phonon.

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There are two methods for calculating the account balances shown on nancial statements and reports. The two methods are the cash basis and the accrual basis. In the cash basis of accounting, revenue is recorded only when cash is received; expenses are recorded only when cash is paid.

Figure 9.1 Schematic illustrations of the atomic displacements in (a) longitudinal acoustic (LA) and (b) transverse acoustic (TA) phonon modes

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